Home › Forums › density functional theory › the Born-Oppenheimer approximation › Situation where the Born-Oppenheimer approximation may not be valid This topic has 0 replies, 1 voice, and was last updated 1 year, 8 months ago by saurish. Viewing 1 post (of 1 total) Author Posts April 7, 2023 at 1:28 am #8475 saurishParticipant At high temperatures, when the equipartition theorem is valid or is approximately valid, the kinetic energies of the nuclei and the electrons should become comparable. Author Posts Viewing 1 post (of 1 total) You must be logged in to reply to this topic. Log In Username: Password: Keep me signed in Log In
.
