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  • in reply to: Question on post-HF methods #8440
    carlosjimenez11
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    Theoretically, the full CI arises with the exact ground state indeed, however, if you take a look on the central equation for CI, you will note that it’s impossible to consider computationally all the possible configurations even for small systems. So, the answer is yes, the full CI solution converges with the ground state, but its not applicable.

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